Gilbert Newton Lewis was born on October 23, 1875 in Weymouth, Massachusetts. His father, Francis Lewis, was a lawyer. When he was nine his parents moved to Lincoln, Nebraska. Lewis had no formal schooling until he was admitted to a preparatory school for the University of Nebraska at the age of 13. He attended the University of Nebraska for two years, then in 1893 he went to Harvard College where he graduated in 1896. After a year of teaching at Philips Academy Andover outside of Boston he returned to Harvard where he earned his MA in 1898 and his PhD in 1899 with a dissertation on electrochemical potentials. He remained at Harvard for on more year as an instructor then went on a traveling fellowship where he visited Wilhelm Ostwald in Leipzig and Walther Nernst in Gottingen. When he returned he spent three more years at Harvard before moving the the Philippines where he was superintendent of weights and measures and chemist at the Bureau of Science.
He returned to the United States in 1905 to a faculty position at the Massachusetts Institute of Technology, where he was appointed assistant professor in 1907, associate professor in 1908, and full professor in 1911. In 1912 he left M.I.T. for the University of California at Berkeley where he was dean of chemistry and a professor of physical chemistry. His time in California was interrupted by First World War when Lewis served as a major in the gas service and chemical warfare service.
His first research interest was thermodynamics. He introduced the idea of activity, or the effective concentration of a chemical species in solution. Lewis is best remembered for his valence theory and the eponymous dot structures. Lewis pictured atoms as cubes with the electrons at the corners. We now know that atoms are spherical and their electrons are spread out in orbitals. Lewis also wrote papers on relativity and defined acids and bases as electron acceptors and electron donators respectively. Lewis was the first to produce deuterium oxide (heavy water) using Ernest Lawrence's cyclotron in 1933.
Honors won by Lewis include election in to the National Academy of Science in 1913. Because of his disagreements with Walther Nernst he was never awarded the Nobel Prize although he was nominated 30 times. He was awarded numerous honorary doctorates and membership in Royal Society, the Chemical Society of London and the Indian, Swedish, and Danish Academies of Science.
On March 23, 1946 Lewis died in a laboratory accident involving hydrogen cyanide which some believed was suicide.
References:
Carey, Charles W.; "Lewis, Gilbert N." in American Scientists; Infobase Publishing; 2006
Hildebrand, Joel H.; "Gilbert Newton Lewis; 1875-1946"; National Academy Press; 1958
Gilbert N. Lewis Wikipedia Entry
Showing posts with label chemical valency. Show all posts
Showing posts with label chemical valency. Show all posts
Sunday, September 15, 2013
Sunday, January 17, 2010
Edward Frankland

Edward Frankland was born on January 18, 1825 at Churchdown, near Garstang in Lancashire the illegitimate son of a prosperous lawer. A percocious learner, he knew his letters by age 2 and at age 3 he was sent to a Dame's school in Manchester, where his mother was staying. He wrote of his devotion to the master, James Willasey, who he later assisted after the school closed and was left in poverty. From Dr. Willasey he learned to speak French without an accent and became interested in physical science. The last school he attended was Lancashire Grammar School where he learned Latin, which he hated.
At age fifteen he was apprenticed to a druggist. Frankland in his writings speaks of the six years of his apprenticeship as wasted time, calling it, "six years' continuous hard labor, from which I derived no advantage whatever, except the facility of tying up parcels neatly." Despite his complaints, he was able to make use of what little free time he had and borrow apparatus from his master to perform some basic experiments with the other apprentices.
In 1845, at the termination of his apprenticeship, Frankland traveled to London, where he was able to gain a position in the laboratory of Dr. Lyon Playfair, who had just been made the chemist to the Government Department of Woods and Forests. Although Dr. Playfair was often absent on official duties, Frankland made friends with his chief assistant, Mr. Ransom, who introduced him to the world of chemical analysis. So rapid was his progress that after six months he was offered the position as Playfair's lecture assistant.
In 1845, at the termination of his apprenticeship, Frankland traveled to London, where he was able to gain a position in the laboratory of Dr. Lyon Playfair, who had just been made the chemist to the Government Department of Woods and Forests. Although Dr. Playfair was often absent on official duties, Frankland made friends with his chief assistant, Mr. Ransom, who introduced him to the world of chemical analysis. So rapid was his progress that after six months he was offered the position as Playfair's lecture assistant.
In 1847 he went to Marburg, Germany, where he briefly worked in the laboratory of Robert Bunsen. But soon had to return to England, where he had a teaching position at the new Queenwood College in Hampshire. The position required him to lecture not only in chemistry but also botany and geology in addition to setting up the school's laboratory. At his new post he also had the opportunity to meet John Tyndal, who later would become a physics professor at the Royal Institution. During this time the two would rise early and while Frankland would study mathematics under Tyndal's direction, Frankland taught Tyndal chemistry.
In 1848 both Frankland and Tyndal traveled to Marburg, where Frankland continued his research and finished his Ph.D. His work on organometalic compounds laid the basis for his discovery of chemical valence. The compounds he was working with, zinc dialkyls, only combined in certain whole number ratios, an idea that Lavosier had found when working with the break down of water. This led Frankland to realize what he called atomicity, that we now call valence, that "the combining power of the attracting element is always satisfied by the same number of atoms." For twenty years he conducted research, from 1848 to 1868, into the nature of the combining capacity or valency of various elements.
The idea of valency is that the various elements all have a fixed number of bonds that they can form. For example hydrogen will always form only one bond, oxygen two, nitrogen three and carbon four. Frankland's legacy is this idea that elements will form a fixed number of chemical bonds, an idea that was slow in being accepted, but now is the basis of structural chemistry.
In 1865 he was appointed professor of the Royal School of Mines at South Kensington and the Royal College of Chemistry. Frankland was knighted in 1897, on the occasion of Queen Victoria's jubilee, for his thirty years of analyzing the pollution in municipal water supplies, a position he was appointed to in 1868. He died two years later on August 9, 1899.
References:
Obituary Notice: William Frankland; American Chemical Journal Vol. 22 (1899) p.410-411
Sir Edward Frankland K.C.B., F.R.S.; Nature Vol. 60 (1899) p.372
Aiado, Tel; Chemist William Frankland; online at great-scientists.suite101.com
Tilden, William; Famous Chemists: The Men and Their Work; George Routledge and Sons; 1921
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